Electrolyzer having radial flowing passage

ABSTRACT

Electrolytic equipment in the form of radiation mode that is provided with pluralities of baffles ( 13 ) in the form of radiation mode on the top surface of the seat ( 10 ) and acidic water passage ( 131 ) is formed between the baffles ( 13 ). The top surface of the seat ( 10 ) has through holes ( 14 ) used to make anode conduction portions ( 33 ) of anode plate ( 30 ) through. In the center of the seat ( 10 ), there is a socket joint portion ( 11 ) that is provided with an inlet and outlet interval tube ( 15 ) in the center of it. There are plurality of equidistributed baffles ( 151, 157 ) on the inside wall and the outside wall of the inlet and outlet interval tube ( 15 ) to form raw water inlet passage ( 152 ) and acidic water outlet passage ( 153 ). There are protuberant ribs ( 16 ) for separating water inside of the seat ( 10 ) corresponding to the location for separating water around the anode plate ( 30 ) and the cathode plate ( 40 ), which are used to separate alkaline water and acidic water electrolyzed from the anode plate ( 30 ) and the cathode plate ( 40 ). Alkaline water passage ( 631 ) is formed on the bottom surface of the lid ( 60 ) and the center of  11   d  ( 60 ) is provided with alkaline water outlet joint ( 61 ).

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to an electrolytic cell or electrolyzer, and more particularly to an electrolytic cell or electrolyzer including a radial flowing passage for suitably separating and collecting anolyte and catholyte from a flowing electrolyte or water, and for preventing the anolyte and the catholyte from being mixed or blended with each other.

2. Description of the Prior Art

Typical electrolytic cells or electrolyzers comprise one or more anodes and one or more cathodes disposed within a cell body or container that is provided for receiving electrolyte therein, for generating anolyte and catholyte by energizing or actuating or operating the anodes and the cathodes when the electrolyte flows through the anodes and the cathodes, and for utilizing the anolyte and the catholyte to electroplate various kinds of work pieces.

In some circumstances, the anolyte and the catholyte are required to be separated from each other, for such as manufacturing or separating chlorine and caustic from brine. Accordingly, one or more separating devices are required to be disposed or engaged into the electrolytic cells or electrolyzers for separating the anolyte and the catholyte from each other in the typical electrolytic cells.

For example, U.S. Pat. No. 4,342,636 to Chang et al. discloses one of the typical electrolytic cells including a porous polyfluoroalkylene sheet disposed therein and acted as a separator for the electrolysis of brine and for separating the anolyte and the catholyte from each other.

However, the typical porous polyfluoroalkylene sheet is good enough for separating the anolyte and the catholyte from each other in a static or motionless electrolyte in the electrolytic cells or electrolyzers, but the typical electrolytic cells or electrolyzers may not be used for separating and collecting the anolyte and the catholyte from the flowing electrolyte or water.

In addition, normally, the inlet ports of the typical electrolytic cells or electrolyzers include a cross section or area identical to the outlet ports of the typical electrolytic cells or electrolyzers for allowing the electrolyte or water to flow in the same flowing speed into and out of the typical electrolytic cells or electrolyzers, such that the outward flowing speed of the electrolyte or water may not be suitably decreased or slowed down.

The present invention has arisen to mitigate and/or obviate the afore-described disadvantages of the conventional electrolytic cells for separating the anolyte and the catholyte from each other.

SUMMARY OF THE INVENTION

The primary objective of the present invention is to provide an electrolytic cell or electrolyzer having a radial flowing passage for suitably separating and collecting the anolyte and the catholyte from the flowing electrolyte and for preventing the anolyte and the catholyte from being mixed or blended with each other.

In accordance with one aspect of the invention, there is provided an electrolyzer comprising a receptacle including a compartment and a chamber formed therein and communicating with each other, and including an inlet port formed therein and communicating with the chamber of the receptacle for receiving an electrolytic solution to be electrolyzed, and including an outlet port formed therein and communicating with the compartment of the receptacle, a housing engaged onto the receptacle for closing the compartment and the chamber of the receptacle, and including a cylindrical member engaged into the receptacle and for separating the compartment and the chamber of the receptacle from each other, and includes a bore formed in the cylindrical member and communicating with the chamber and the inlet port of the receptacle, and including a peripheral channel formed in an outer peripheral portion of the cylindrical member and formed between the cylindrical member and the housing, and including a space formed in an outer peripheral wall of the housing and communicating with the peripheral channel of the housing, the housing including a plurality of radially extended ribs extended in the space of the housing, and including a separator tip extended from the outer peripheral wall into the space of the housing, a cover engaged onto the housing for closing the space of the housing, and including a chamber formed therein, a cathode plate and an anode plate disposed in the space of the housing and disposed horizontally and arranged one above the other, and spaced from each other for forming a gap between the anode plate and the cathode plate, and arranged for guiding the electrolytic solution to flow radially through the gap formed between the anode plate and the cathode plate, the separator tip of the housing being disposed around the anode plate and the cathode plate and extended toward the gap, a conductor tube engaged through the bore of the cylindrical member and extended out of the receptacle, and electrically coupled to the cathode plate, and the cathode plate is provided for attracting an anolyte of the electrolytic solution toward the cathode plate, and the anode plate is provided for attracting a catholyte of the electrolytic solution toward the anode plate, and for allowing the anolyte and the catholyte to be separated from each other with the separator tip of the housing.

The housing includes at least one spacer extended radially from the outer peripheral wall into the space of the housing for engaging with the cathode plate and for anchoring and positioning the cathode plate to the housing.

The cathode plate includes at least one finger extended radially and outwardly of the cathode plate for engaging with the spacer of the housing and for anchoring the cathode plate to the housing. The cover is secured to the housing with a threading engagement.

The housing includes a plurality of outlet ports formed in the housing and communicating with the peripheral channel of the housing for guiding the electrolytic solution to flow from the space into the peripheral channel of the housing and into the compartment of the receptacle.

The housing includes at least one fin extended into the bore of the cylindrical member. The housing includes at least one fin extended out of the cylindrical member for engaging with the receptacle.

The housing includes at least one orifice formed therein and communicating with the space of the housing, and the anode plate includes at least one electrode extended therefrom for engaging out through the orifice of the housing.

The cathode plate includes a bore formed therein, and the conductor tube is engaged through the bore of the cathode plate and secured to the cathode plate. The cover includes a plurality of ribs extended radially for guiding the anolyte. The cover has an outlet mouth communicating with the chamber of the cover.

Further objectives and advantages of the present invention will become apparent from a careful reading of the detailed description provided hereinbelow, with appropriate reference to the accompanying drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a perspective view of an electrolytic cell or electrolyzer in accordance with the present invention having a radial flowing passage, in which one half of the electrolytic cell or electrolyzer has been cut off for showing an inner structure of the electrolytic cell or electrolyzer;

FIG. 2 is an exploded view of the electrolytic cell or electrolyzer, as seen from the upper portion of the electrolytic cell or electrolyzer;

FIG. 3 is another exploded view of the electrolytic cell or electrolyzer, as seen from the bottom portion of the electrolytic cell or electrolyzer;

FIG. 4 is a cross sectional view of the electrolyzer as seen from one side portion of the electrolytic cell or electrolyzer of that shown in FIG. 1;

FIG. 5 is a cross sectional view of the electrolyzer taken along lines 5-5 of FIG. 4;

FIG. 6 is another perspective view similar to FIG. 1, illustrating the other arrangement of the electrolyzer;

FIG. 7 is a cross sectional view of the electrolyzer as shown in FIG. 6;

FIG. 8 is a further perspective view similar to FIGS. 1 and 6, illustrating the further arrangement of the electrolyzer;

FIG. 9 is a cross sectional view of the electrolyzer as shown in FIG. 8;

FIG. 10 is a still further perspective view similar to FIGS. 1, 6 and 8, illustrating the still further arrangement of the electrolyzer;

FIG. 11 is an exploded view as seen from the upper portion of the electrolyzer as that shown in FIG. 10;

FIG. 12 is an exploded view as seen from the bottom portion of the electrolyzer as that shown in FIG. 10;

FIG. 13 is a cross sectional view of the electrolyzer as seen from one side portion of the electrolytic cell or electrolyzer of that shown in FIG. 10;

FIG. 14 is a cross sectional view of the electrolyzer taken along lines 14-14 of FIG. 13;

FIG. 15 is a diagram illustrating the changing of the flowing speed of the flowing electrolyte or water; and

FIG. 16 is another diagram illustrating the changing of the electric current of the flowing electrolyte or water.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT

Referring to the drawings, and initially to FIGS. 1-4, an electrolytic cell or electrolyzer 1 in accordance with the present invention comprises a receptacle 70 including an enlarged upper compartment 71 formed in the upper portion thereof, and including a chamber 74 formed in the middle portion thereof and defined by an inner peripheral surface 72 and communicating with the upper compartment 71 of the receptacle 70, and including a reduced or narrowed conduit 75 formed in the lower portion thereof and communicating with the middle chamber 74 of the receptacle 70, and including a first or outlet port 77 formed therein and communicating with the compartment 71 of the receptacle 70 for receiving such as water or brine or other electrolytic solutions, and including a second or inlet port 78 formed therein and also communicating with the chamber 74 of the receptacle 70, and including an inner peripheral shoulder 79 formed in the lower portion thereof.

A housing 10, such as a lower housing 10 includes a casing 11 extended downwardly therefrom for engaging into and for closing the compartment 71 and the middle chamber 74 of the receptacle 70, and includes one or more studs 12 for securing to the receptacle 70, and includes a sleeve or cylindrical member 15 extended into the casing 11 and also extended downwardly from the casing 11 for engaging into the chamber 74 of the receptacle 70 and for separating the compartment 71 and the chamber 74 of the receptacle 70 from each other (FIGS. 1, 4), and includes a bore 152 formed in the cylindrical member 15 for communicating with the chamber 74 and the port 78 of the receptacle 70 (FIGS. 1, 4), and includes a peripheral channel 153 formed in the inner peripheral portion of the casing 11, or formed in the outer peripheral portion of the cylindrical member 15, and formed or located between an upper portion of the cylindrical member 15 and the casing 11 of the housing 10, and includes an upper space 131 formed therein and communicating with the peripheral channel 153 of the casing 11 or of the housing 10.

The housing 10 includes a number of radially extended fins 151 extended into the bore 152 of the cylindrical member 15, and includes a number of radially extended fins 157 radially extended out of the cylindrical member 15 for engaging with the receptacle 70 and for anchoring or positioning the housing 10 to the receptacle 70, and includes a number of radially extended ribs 13 extended in the space 131 of the housing 10 and extended from the outer peripheral portion of the cylindrical member 15 to the outer peripheral portion of the housing 10, and extended into the peripheral channel 153 of the casing 11 or of the housing 10, and includes one or more outlet ports 154 formed in the casing 11 and communicating with the peripheral channel 153 of the casing 11 or of the housing 10 for guiding the electrolytic solution or water to flow from the space 131 into the peripheral channel 153 of the casing 11 or of the housing 10 and into the compartment 71 of the receptacle 70, and then to flow out through the port 77 of the receptacle 70.

The cylindrical member 15 of the housing 10 may be solidly secured to the receptacle 70 with such as force-fitted engagements, adhesive materials, or by welding processes, and the housing 10 further includes one or more, such as four orifices 14 formed therein and communicating with the space 131 of the housing 10, and includes a peripheral recess 155 and a peripheral shoulder 156 formed in the upper or inner portion of the cylindrical member 15 of the housing 10, and includes a separator tip 16, such as an inner peripheral and separator tip 16 extended from an outer peripheral wall 101 into the space 131 of the housing 10, and includes one or more spacers 161, 162 and one or more protrusions 163, 164 extended radially from the outer peripheral wall 101 into the space 131 of the housing 10, and includes an outer thread 17 formed on the outer peripheral portion of the peripheral wall 101 of the housing 10, and includes an inner peripheral shoulder 18 formed in the inner portion of the peripheral wall 101 of the housing 10.

One or more sealing rings Q1 may be provided and engaged between the casing 11 of the housing 10 and the receptacle 70 for making a water tight seal between the casing 11 of the housing 10 and the receptacle 70, and one or more sealing rings Q2 may be provided and engaged between the cylindrical member 15 of the housing 10 and the receptacle 70 for making a water tight seal between the cylindrical member 15 of the housing 10 and the receptacle 70 for suitably guiding the electrolytic solution or water to flow from the second or inlet port 78 of the receptacle 70 into the middle chamber 74 of the receptacle 70, and then to flow into the bore 152 of the cylindrical member 15, and then to flow into the space 131 of the housing 10; and the electrolytic solution or water may flow from the space 131 of the housing 10 into the peripheral channel 153 of the casing 11 or of the housing 10 and flow through the outlet ports 154 of the casing 11 and then flow into the compartment 71 of the receptacle 70, and then flow out through the port 77 of the receptacle 70.

A cover 60 may be provided and engaged or attached or secured onto the housing 10 and includes an inner thread 64 formed therein for threading or engaging with the outer thread 17 of the housing 10 and for closing the space 131 of the housing 10. The cover 60 includes a peripheral fence 66 extended downwardly from the outer peripheral portion thereof for engaging onto or into the peripheral wall 101 of the housing 10 with the threading engagement 64, 17, and includes a compartment 62 formed therein, and includes a number of radially extended ribs 63 extended into the compartment 62 and/or a chamber 631 of the cover 60 and extended from the inner peripheral portion to the outer peripheral portion of the cover 60 for guiding the electrolytic solution or water to flow from the chamber 631 into the compartment 62 and then to flow out through an outlet mouth 61 of the cover 60 which is communicating with the chamber 631 and/or the compartment 62 of the cover 60. The compartment 62 and the chamber 631 of the cover 60 and the space 131 of the housing 10 may be provided for receiving the electrolytic solution or water to be treated or to be electrolyzed. The cover 60 includes an inner peripheral shoulder 65 formed therein for engaging with one or more sealing rings Q4 may be engaged with the housing 10 for making a water tight seal between the housing 10 and the cover 60.

An anode plate 30 is disposed or engaged into the space 131 of the housing 10 and disposed or engaged onto or seated or supported on the upper portion of the ribs 13 of the housing 10, and includes one or more (such as four) electrodes 33, such as positive electrodes 33, extended therefrom for engaging out through the orifices 14 of the housing 10 respectively and for coupling to such as the positive electric power source (not shown), and includes a center hole 31 formed therein and defined by a peripheral fence 32 for receiving or engaging with the peripheral recess 155 of the cylindrical member 15 and the housing 10 and for allowing the electrolytic solution or water to be guided to flow upwardly through the center hole 31 of the anode plate 30 and thus for allowing the electrolytic solution or water to be treated or electrolyzed by the anode plate 30. One or more sealing rings Q3 may be provided and engaged in the peripheral shoulder 156 of the cylindrical member 15 and engaged between the cylindrical member 15 of the housing 10 and the anode plate 30 for making a water tight seal between the housing 10 and the anode plate 30.

A cathode plate 40 is disposed or engaged into the space 131 of the housing 10 or into the compartment 62 of the cover 60 and disposed or engaged onto or seated on the bottom portion of the ribs 63 of the cover 60, and includes a bore 41 formed therein for receiving or engaging with a conductor tube 20 which may include a peripheral shoulder 22 and a threaded member or screw or fastener 21 for engaging with a fastener or nut 50 or which may be solidly secured to the cathode plate 40 with such as force-fitted engagements, adhesive materials, or by welding processes. The cathode plate 40 includes an inner peripheral recess 42 formed therein for receiving or engaging with another sealing ring Q5 which may be engaged between the conductor tube 20 and the cathode plate 40 for making a water tight seal between the conductor tube 20 and the cathode plate 40, and may include one or more fingers 43 extended radially and outwardly of the cathode plate 40 for engaging with either of the spacers 161, 162 and/or the protrusions 163, 164 of the housing 10 (FIG. 5) and for anchoring or positioning or securing the cathode plate 40 to the housing 10.

The conductor tube 20 is engaged through the bore 152 of the cylindrical member 15 and extended out of the conduit 75 of the receptacle 70, and one or more sealing rings Q6, Q7 may be provided and engaged between the conductor tube 20 and the conduit 75 of the receptacle 70 for making a water tight seal between the conductor tube 20 and the conduit 75 of the receptacle 70. As shown in FIGS. 1 and 4, the conductor tube 20 is electrically coupled to the cathode plate 40 and coupled to the negative electric power source for actuating the cathode plate 40 to generate an anolyte 99 (FIG. 4) which may flow into the chamber 631 and the compartment 62 of the cover 60 (FIG. 5) and then may flow out through the outlet mouth 61 of the cover 60.

As also shown in FIG. 4, the electrolytic solution or water may flow through the second or inlet port 78 and into the chamber 74 of the receptacle 1, and may then flow through the bore 152 of the cylindrical member 15, and may then be guided to flow through the gap 9 that is formed between the anode plate 30 and the cathode plate 40 and to flow radially from the center portions the anode plate 30 and the cathode plate 40 toward the outer peripheral portion of the anode plate 30 and the cathode plate 40, such that the flowing speed of the electrolytic solution may be gradually decreased or slowed down from the center portions toward the outer peripheral portion of the anode plate 30 and the cathode plate 40 for preventing an eddy current from being generated between the anode plate 30 and the cathode plate 40.

It is preferable, but not necessarily that the outer peripheral portion of the anode plate 30 may be slightly bent or tilted downwardly or further spaced away from the cathode plate 40, and/or the outer peripheral portion of the cathode plate 40 may be slightly bent or tilted upwardly or further spaced away from the anode plate 30 for further increasing the volume between the outer peripheral portion of the anode plate 30 and the cathode plate 40 and for further decreasing the flowing speed of the electrolytic solution and thus for further preventing the eddy current from being generated between the anode plate 30 and the cathode plate 40, and thus for allowing the electrolytic solution to smoothly flow through the gap 9 that is formed between the anode plate 30 and the cathode plate 40.

In operation, as also shown in FIG. 4, the electrolytic solution may be supplied and flown into the receptacle 70 via the inlet port 78 of the receptacle 70, and then flowing through the bore 152 of the cylindrical member 15 and the center hole 31 of the anode plate 30 and then guided to flow through the gap 9 that is formed between the anode plate 30 and the cathode plate 40. When the cathode plate 40 and the anode plate 30 are energized or actuated or operated, the anolyte 99 may be generated and attracted toward the cathode plate 40 and may thus be forced or attracted to flow closer to the cathode plate 40, and the catholyte 88 may be generated and attracted toward the anode plate 30 and may thus be forced or attracted to flow closer to the anode plate 30.

The annular separator tip 16 is disposed or provided in the housing 10 and disposed around the anode plate 30 and the cathode plate 40, or extended into the compartment 62 of the cover 60 and extended toward the gap 9, such as toward the middle or intermediate portion of the gap 9 that is formed between the anode plate 30 and the cathode plate 40, best shown in FIG. 4, for suitably separating the anolyte 99 and the catholyte 88 from each other and for preventing the anolyte 99 and the catholyte 88 from being mixed or blended with each other. The anolyte 99 may be generated and attracted toward the cathode plate 40 and may thus be forced or caused or attracted to flow closer to the cathode plate 40, and may then be guided to flow into the compartment 62 of the cover 60 by the cathode plate 40 itself and/or by the separator tip 16 and may then be guided to flow out through the outlet mouth 61 of the cover 60, and then for allowing the anolyte 99 to be collected for further use.

Simultaneously, the catholyte 88 may be generated and attracted toward the anode plate 30 and may thus be forced or caused to flow closer to the anode plate 30, and may then be guided to flow into the into the space 131 of the housing 10, and to flow into the peripheral channel 153 of the casing 11 or of the housing 10, and to flow out through the outlet ports 154 of the casing 11 and then to flow into the compartment 71 of the receptacle 70, and then to flow out through the outlet port 77 of the receptacle 70, for allowing the catholyte 88 to be collected for further use. The cathode plate 40 and the anode plate 30 may thus be used for generating the anolyte 99 and the catholyte 88 respectively, and for guiding the catholyte 88 to flow out through the outlet port 77 of the receptacle 70, and for guiding the anolyte 99 to flow out through the outlet mouth 61 of the cover 60. The separator tip 16 may thus be acted as a separating means or device for separating the anolyte 99 and the catholyte 88 away from each other, and for effectively guiding the catholyte 88 and the anolyte 99 to flow into the space 131 of the housing 10 and the chamber 631 and the compartment 62 of the cover 60 respectively.

As shown in FIG. 15, the anolyte 99 and the catholyte 88 or the electrolytic solution may be forced to flow radially from the center portion the anode plate 30 and the cathode plate 40 toward the outer peripheral portion of the anode plate 30 and the cathode plate 40, such that the flowing speed of the electrolytic solution may be gradually slowed down or decreased from the center portion toward the outer peripheral portion of the anode plate 30 and the cathode plate 40, and the skin effect (L/M) Sa, Sb, Sc, Sd, Se . . . may also be gradually decreased from the center portion toward the outer peripheral portion of the anode plate 30 and the cathode plate 40, and the electric current (I) Ia, Ib, Ic, Id, Ie . . . may be gradually increased from the center portion toward the outer peripheral portion of the anode plate 30 and the cathode plate 40 as shown in FIG. 16.

Alternatively, as shown in FIGS. 6-7, the housing 10 may also include a sleeve or cylindrical member 15 extended downwardly therefrom for engaging into the chamber 74 of the receptacle 70 and also includes a space 131 communicating with the bore 152 of the cylindrical member 15 and defined by a peripheral wall 101, and includes a number of radially extended ribs 13 extended into the space 131 of the housing 10 for guiding the electrolytic solution or water to flow from the space 131 into the peripheral channel 153 of the casing 11 or of the housing 10. A cover 60 may also be secured onto the housing 10 with such as a threaded engagement 64, and also includes a compartment 62 formed therein, but has no outlet mouth provided thereon. The anode plate 30 is also disposed or engaged into the compartment 62 of the cover 60 and/or disposed or engaged into the space 131 of the housing 10, and/or disposed or engaged onto or seated on the ribs 13 of the housing 10, and the cathode plate 40 is disposed or engaged onto or seated on the ribs 63 of the cover 60 and includes bore 41 formed therein for receiving or engaging with a conductor tube 201 which may be solidly secured to the cathode plate 40 with a fastener 50. The conductor tube 201 is engaged through the bore 152 of the cylindrical member 15 and extended out of the conduit 75 of the receptacle 70.

The electrolytic solution may also be supplied and flown into the receptacle 70 via the inlet port 78, and then flowing through the bore 152 of the cylindrical member 15 and then guided to flow through the gap 9 that is formed between the anode plate 30 and the cathode plate 40, and to flow radially from the center portions the anode plate 30 and the cathode plate 40 toward the outer peripheral portion of the anode plate 30 and the cathode plate 40, such that the flowing speed of the electrolytic solution may also be gradually decreased or slowed down from the center portions toward the outer peripheral portion of the anode plate 30. The anolyte 99 may be generated and attracted toward the cathode plate 40 and may thus be forced or attracted to flow closer to the cathode plate 40, and the catholyte 88 may be generated and attracted toward the anode plate 30 and may thus be forced pr attracted to flow closer to the anode plate 30 when the cathode plate 40 and the anode plate 30 are energized or actuated or operated.

The conductor tube 201 includes a bore 23 formed therein for receiving the anolyte 99 from the compartment 62 of the cover 60 and for guiding the anolyte 99 to flow out through the bore 23 of the conductor tube 201 and for allowing the anolyte 99 to be collected for further use. The annular separator tip 16 may also be disposed or arranged around the anode plate 30 and the cathode plate 40, and extended into the space 131 of the housing 10 or extended into the compartment 62 of the cover 60 and extended toward the gap 9, such as toward the middle or intermediate portion of the gap 9 that is formed between the anode plate 30 and the cathode plate 40 for suitably separating the anolyte 99 and the catholyte 88 from each other and for preventing the anolyte 99 and the catholyte 88 from being mixed or blended with each other.

Further alternatively, as shown in FIGS. 8-9, the housing 102 has no separator tip provided therein, instead, an ion exchanging film or membrane 100 is disposed or arranged in the gap 9 that is formed between the anode plate 30 and the cathode plate 40 for suitably separating the anolyte 99 and the catholyte 88 from each other and for preventing the anolyte 99 and the catholyte 88 from being mixed or blended with each other. The conductor tube 202 also includes a bore 26 formed therein for receiving the anolyte 99 from the compartment 62 of the cover 60 and for guiding the anolyte 99 to flow out through the bore 26 of the conductor tube 202, best shown in FIG. 9, and for allowing the anolyte 99 to be collected for further use.

Further alternatively, as shown in FIGS. 10-14, the housing 103, the receptacle 700, the cover 601, the anode plate 30 and the cathode plate 40 are disposed up side down or disposed reversely, and the housing 103 also includes a separator tip 16 extended from the housing 103 and disposed around the anode plate 30 and the cathode plate 40, or extended toward the middle or intermediate portion of the gap 9 that is formed between the anode plate 30 and the cathode plate 40 for suitably separating the anolyte 99 and the catholyte 88 from each other. The housing 103 includes a catch 111 (FIG. 11) for engaging with a latch groove 701 of the receptacle 700 for quickly and detachably coupling or securing the housing 103 and the receptacle 700 together, and the receptacle 700 includes two sockets 81 for receiving springs S1 and conductors 82, and two caps 83 secured to the sockets 81 for retaining the springs S1 and the conductors 82 in the sockets 81, and the conductors 82 may be biased by the springs S1 to electrically couple to the positive electrodes 33 of the anode plate 30.

The receptacle 700 further includes an electric connecting device 80 having a casing 84 provided therein for receiving another conductor 85, a fastener or lock nut N is attached or secured onto the conductor 85 for anchoring or retaining the conductor 85 to the casing 84 and the receptacle 700 and for preventing the conductor 85 from being disengaged from the casing 84 and the receptacle 700, and a spring member S2 may be provided and engaged into the casing 84 and engaged with the conductor 85 for biasing and forcing the conductor 85 to engage with the conductor tube 20. The cover 601 includes an outlet mouth 611 for allowing the anolyte 99 to flow out through the outlet mouth 611 of the cover 601, and then for allowing the anolyte 99 to be collected for further use.

A check valve 90 includes a container 91 secured to the cover 601 with a threading engagement 92 and having an opening 95 formed therein, a gasket 93 disposed in the container 91 and having a valve seat 96 provided therein for engaging with a ball or detent 94, and a spring member S3 is engaged with the ball or detent 94 for biasing and forcing the detent 94 to selectively engage with the valve seat 96 and to selectively block the opening 95 of the container 91 and arranged to allow the anolyte 99 to flow out through the outlet mouth 611 of the cover 601 only, and to prevent the anolyte 99 from flowing backwardly from the outlet mouth 611 of the cover 601 into the chamber 631 and the compartment 62 of the cover 601.

Accordingly, the electrolyzer may be provided for suitably separating and collecting the anolyte and the catholyte from the flowing electrolyte and for preventing the anolyte and the catholyte from being mixed or blended with each other.

Although this invention has been described with a certain degree of particularity, it is to be understood that the present disclosure has been made by way of example only and that numerous changes in the detailed construction and the combination and arrangement of parts may be resorted to without departing from the spirit and scope of the invention as hereinafter claimed. 

1. An electrolyzer comprising: a receptacle including a compartment and a chamber formed therein and communicating with each other, and including an inlet port formed therein and communicating with said chamber of said receptacle for receiving an electrolytic solution to be electrolyzed, and including an outlet port formed therein and communicating with said compartment of said receptacle, a housing engaged onto said receptacle for closing and said compartment and said chamber of said receptacle, and including a cylindrical member engaged into said receptacle and for separating and compartment and said chamber of said receptacle from each other, and includes a bore formed in said cylindrical member and communicating with said chamber and said inlet port of said receptacle, and including a peripheral channel formed in an outer peripheral portion of said cylindrical member and formed between said cylindrical member and said housing, and including a space formed in an outer peripheral wall of said housing and communicating with said peripheral channel of said housing, said housing including a plurality of radially extended ribs extended in said space of said housing, and including a separator tip extended from said outer peripheral wall into said space of said housing, a cover engaged onto said housing for closing said space of said housing, and including a chamber formed therein, a cathode plate and an anode plate disposed in said space of said housing and disposed horizontally and arranged one above the other, and spaced from each other for forming a gap between said anode plate and said cathode plate, and arranged for guiding the electrolytic solution to flow radially through said gap formed between said anode plate and said cathode plate, said separator tip of said housing being disposed around said anode plate and said cathode plate and extended toward the gap, a conductor tube engaged through said bore of said cylindrical member and extended out of said receptacle, and electrically coupled to said cathode plate, and said cathode plate being provided for attracting an anolyte of the electrolytic solution toward said cathode plate, and said anode plate being provided for attracting a catholyte of the electrolytic solution toward said anode plate, and for allowing the anolyte and the catholyte to be separated from each other with said separator tip of said housing.
 2. The electrolyzer as claimed in claim 1, wherein said housing includes at least one spacer extended radially from said outer peripheral wall into said space of said housing for engaging with said cathode plate and for anchoring and positioning said cathode plate to said housing.
 3. The electrolyzer as claimed in claim 1, wherein said cathode plate includes at least one finger extended radially and outwardly of said cathode plate for engaging with said at least one spacer of said housing and for anchoring said cathode plate to said housing.
 4. The electrolyzer as claimed in claim 1, wherein said cover is secured to said housing with a threading engagement.
 5. The electrolyzer as claimed in claim 1, wherein said housing includes a plurality of outlet ports formed in said housing and communicating with said peripheral channel of said housing for guiding the electrolytic solution to flow from said space into said peripheral channel of said housing and into said compartment of said receptacle.
 6. The electrolyzer as claimed in claim 1, wherein said housing includes at least one fin extended into said bore of said cylindrical member.
 7. The electrolyzer as claimed in claim 1, wherein said housing includes at least one fin extended out of said cylindrical member for engaging with said receptacle.
 8. The electrolyzer as claimed in claim 1, wherein said housing includes at least one orifice formed therein and communicating with said space of said housing, and said anode plate includes at least one electrode extended therefrom for engaging out through said at least one orifice of said housing.
 9. The electrolyzer as claimed in claim 1, wherein said cathode plate includes a bore formed therein, and said conductor tube is engaged through said bore of said cathode plate and secured to said cathode plate.
 10. The electrolyzer as claimed in claim 1, wherein said cover includes a plurality of ribs extended radially for guiding the anolyte.
 11. The electrolyzer as claimed in claim 1, wherein said cover has an outlet mouth communicating with said chamber of said cover.
 12. The electrolyzer as claimed in claim 1, wherein said receptacle includes a socket for receiving a spring.
 13. The electrolyzer as claimed in claim 12, wherein said housing includes a catch for engaging with a latch groove of said receptacle and for detachably coupling said housing and said receptacle together, and said receptacle includes a conductor and two caps secured to said socket for retaining said spring and said conductor in said socket, and said conductor is biased by said spring to electrically couple to said positive electrode of said anode plate.
 14. The electrolyzer as claimed in claim 1, wherein said receptacle includes an electric connecting device having a casing for receiving a conductor.
 15. An electrolyzer comprising a housing, a cover, an anode plate, a cathode plate, a conductor tube, a receptacle, wherein: said housing includes a plurality of radially extended ribs on an upper portion, for forming an upper space between said ribs, said housing includes an orifice formed therein for engaging with a positive electrode of said anode plate, said housing includes a casing, and a cylindrical member extended from said casing and having fins extended on inner and outer portions for forming water flowing passages, a separator trip provided on an outer portion of said anode plate and said cathode plate for separating the anolyte and the catholyte from each other, said cover includes a chamber formed in the bottom, and includes an outlet mouth, said anode plate is disposed above and ribs of said housing, and includes a center hole, and includes a plurality of electrodes extended therefrom. said cathode plate is disposed below said ribs of said housing, and includes a bore formed therein for engaging with said conductor tube, said conductor tube is secured to said bore of said cathode plate for coupling to a negative electric power source, said receptacle includes a compartment and a peripheral surface and a peripheral shoulder of different inner diameter, for engaging with said casing of said housing and said conductor tube, and includes an outlet port and an inlet port corresponding to said bore and said peripheral channel of said housing, in operation, water is supplied to said inlet port of said receptacle and said hole of said anode plate for generating an anolyte and a catholyte with said cathode plate and said anode plate respectively, and the anolyte and the catholyte flow radially and outwardly to an outer peripheral portion of said cathode plate and said anode plate and separated by said separator tip, and guided to flow through said peripheral channel and said chamber of said housing and said cover respectively, and then guided to flow through said outlet mouth of said cover and said outlet port of said receptacle respectively.
 16. The electrolyzer as claimed in claim 15, wherein said housing includes at least one spacer extended radially and located below said cathode plate for engaging with said cathode plate, and two protrusions disposed beside said at least one spacer, said cathode plate includes at least one finger extended radially and outwardly of said cathode plate for engaging with said at least one spacer of said housing and for spacing said cathode plate from said anode plate at a smallest spacing distance.
 17. The electrolyzer as claimed in claim 16, wherein said housing includes at least one second spacer disposed beside said at least one spacer, and at least one protrusion disposed beside said at least one second spacer.
 18. The electrolyzer as claimed in claim 15, wherein said anode plate includes at least one fence and said cathode plate includes a peripheral recess for reinforcing purposes.
 19. The electrolyzer as claimed in claim 15, wherein said anode plate and said cathode plate are changeable with each other.
 20. The electrolyzer as claimed in claim 15, wherein said housing, said cover, said anode plate and said cathode plate are circular, and said housing is threaded to said cover.
 21. The electrolyzer as claimed in claim 15, wherein said housing includes a plurality of equally spaced outlet ports formed and located below said peripheral channel, said receptacle includes a chamber formed therein corresponding to said outlet ports of said housing, said cover includes a compartment formed around said outlet mouth.
 22. The electrolyzer as claimed in claim 15, wherein said outlet mouth of said cover is blocked, said conductor tube includes a center bore for receiving the anolyte.
 23. The electrolyzer as claimed in claim 15, wherein said anode plate and said cathode plate are separated from each other with a membrane in stead of said separator tip.
 24. The electrolyzer as claimed in claim 15, wherein said housing is disposed in the upper portion, and said cover is disposed below said housing, and a check valve is secured to said outlet moth of said cover.
 25. The electrolyzer as claimed in claim 24, wherein said check valve includes a container having a gasket and a detent disposed therein, and includes a valve seat, and a plurality of passages around said valve seat.
 26. The electrolyzer as claimed in claim 25, wherein said container includes a spring member disposed therein for biasing said detent to block said valve seat.
 27. The electrolyzer as claimed in claim 24, wherein said housing includes a catch for engaging with a latch groove of said receptacle and for detachably coupling said housing and said receptacle together, and said receptacle includes a socket and a casing for engaging with said electrode and said conductor tube, said socket includes a conductor and a spring and blocked with said cover, said conductor is biased by said spring to electrically couple to said positive electrode of said anode plate, said casing includes a second spring member and a second conductor which is biased by said second spring member to electrically couple to said conductor tube.
 28. The electrolyzer as claimed in claim 15, wherein said cover includes a plurality of radially extended ribs for forming a chamber in said cover. 